Posts filed under 'Colligative Properties of Solution'

Why Is Aluminiums Boiling Point Much Higher Than That Of Magnesium?

I know that Al unlike Mg has one electron in its 3p subshell so why would this increase its boiling point? Thanks!

3 comments May 12th, 2009

If Methyl Alcohol Boils At 84 Degrees On The Hyde Scale, What Is Its Boiling Point On The Jekyll Scale?

On a new Jekyll temperature scale, water freezes at 17 degrees and boils at 97 degrees. On another new temperature scale, the Hyde scale, water freezes at 0 degrees and boils at 120 degrees.
Heres the question, How do I figure this out???
If methyl alcohol boils at 84 degrees on the Hyde scale, what is its boiling point on the Jekyll scale?

2 comments May 12th, 2009

How to calculate the vapor pressure of the water in the urea solution?

Chemistry Tutor Site - Chemistry Homework Help

A 650 ml aqueous solution contains 70 g of urea CO(NH2)2. The vapor pressure of pure water at 20.0 degrees C is 17.5 mm Hg. What is the vapor pressure of the water in the urea solution? (assume that the molar concentration of water in this solution is 55.5 M)

Chemistry Tutor Site - Chemistry Homework Answer

Moles urea = 70 g /60.07 g/mol =1.17

Moles water = 55.5 x 0.650 L =36.1

Mole fraction water = 36.1 / 36.1 + 1.17 =0.969

p = p°X = 17.5 x 0.969 = 17.0 mm Hg

Add comment October 14th, 2008

Calculation Involve of Vapor Pressure

Chemistry Tutor Site - Chemistry Homework Help

At 20˚C the vapor pressure of benzene is 75 torr, and the vapor pressure of toluene is 22 torr.

(a) A solution is prepared from 1.0 mole of biphenyl, a nonvolatile solute, and 49.0 moles of benzene. How do I calculate the vapor pressure of the solution at if the temp. is at 20˚C.

(b)A second solution is prepared from 3.0 moles of toluene and 1.0 mole of benzene. How do I determine the vapor pressure of this solution and the mole fraction of benzene in the vapor?

Chemistry Tutor Site - Chemistry Homework Answer

(a) From Raoult’s law: Vapour pressure = mole fraction in liquid * SVP

For benzene:
Vapour pressure = 49/(1+49) * 75 = 73.5 torr

The biphenyl is involatile so its vapour pressure is 0 torr.

Vapour pressure of solution = 0 + 73.5 = 73.5 torr

b) Using the same equation:

For toluene:
Vapour pressure = 3/(3+1) * 22 = 16.5 torr

For benzene:
Vapour pressure = 1/(3+1) * 75 = 18.75 torr

Vapour pressure of solution = 16.5 + 18.75 = 35.25 torr

Now, using Dalton’s law:
Partial pressure = mole fraction in vapour phase * total pressure
Mole fraction = Partial pressure / total pressure = 18.75 / 35.25 = 0.532

Add comment October 14th, 2008

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